Mekakucity Actors airs every Saturday.
As with all shippings, the KidoxKano relationship is made up by fans (though I would love seeing them get together). Same with Seto and Mary. The only really sort of real shipping in KagePro (well, there's sort of two) is Shintaro x Ayano, as shown in Lost Time Memory (Route XX Shintaro, aka suicidal Shintaro, can't get over Ayano's death), and Ene (Takane) x Konoha (Haruka), shown in Yuukei Yesterday (Ene/Takane had a crush on Haruka/Konoha, it sort of was the same the other way around but then they both...died. Much death in this series).
Yuri's story was really painful to watch. I'm really curious about Kanade's and Shiina's backstories, I know a little bit but not much.