there's no way to tell from the stats, but since it's level 65 it means that it has been in fights, and thus it has EV's. Go to the Sunnyshore sitcker market and ask the lady when your Electivire is in the front spot. if she gives you a ribbon, your Electivire is full on EV's. It's gained 15 levels, so it probobally is.
Sorry, but I think that Electivire is scrwed. It's also from PBR, so it's probobally trash. It would take a lot of Soft Reseting to get a good Electivire from PBR, and if you had you would have posted it's IV's, which you didn't. So I'm pretty certain that this Electivire isn't gonna work out.
If he absolutely wants to use this one he can still use Berries and try to put back some EVs at the right places.
But personnally, I'd just get another one. =/
You're right here.