Ophie
Salingerian Phony
Though it won't break your game, there have been reports that a wild Cherrim, once it turns into Sunshine Forme, becomes impossible to catch. People have depleted their entire stocks of Poké Balls (of every kind), and it breaks out every time no matter how many attempts were made.
And while I'm not sure if it's dumb luck, it may be that Alpha Bronzong in the Coronet Highlands (the fixed spawn to the north of the Mountain Camp) is glitched similarly, but to a lesser extent. It broke out of all of my Ultra Balls and Gigaton Balls despite being lower-leveled than my Pokémon, but it was caught in the first Great Ball I threw. Thus, it is possible that Alpha Bronzong is immune to Ultra Balls and everything of the sort, but not Great Balls.
UPDATE: The 1.0.2 patch has fixed this glitch. You can now catch Cherrim even after it changes to Sunshine Forme.
And while I'm not sure if it's dumb luck, it may be that Alpha Bronzong in the Coronet Highlands (the fixed spawn to the north of the Mountain Camp) is glitched similarly, but to a lesser extent. It broke out of all of my Ultra Balls and Gigaton Balls despite being lower-leveled than my Pokémon, but it was caught in the first Great Ball I threw. Thus, it is possible that Alpha Bronzong is immune to Ultra Balls and everything of the sort, but not Great Balls.
UPDATE: The 1.0.2 patch has fixed this glitch. You can now catch Cherrim even after it changes to Sunshine Forme.
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