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Nidoqueen is a defender, and her defenses can take a few hits to Psychics and she has higher HP than Nidoking, so Nidoqueen gets my vote. She can also use a few defensive attacks to stall the match, and Nidoking gets easily KO'ed by Water, Ground and Psychic Pokémon (he's better at Speed, Attack and Sp. Attack, AFAIK).
I prefer Nidoking. I like offensive Pokémon more than defensive ones, I had one on my old Yellow version that helped me a lot, and of course, my dear Nidokingu makes me connect Nidoking with teh cuteness. :3
I prefer Nidoking because his attacking power. I do think Nidoqueen is absolutely adorable, though... *lub* *pokes the above post and snickers* You're cute...
Anyway, It'd normally be a tie, since I use both, but I prefer Attack over Defence, so there ya go.