Here all my sets, thought of them myself...
Cool:
Skarmory
- Swift
- Agility
- Peck or something
Swift when you start first otherwise Peck , Agility , Swift , Agility , Swift
Plusle and Minun (can be done with all electrics knowing QA)
- Quick Attack
- Shock Wave
- Thunderbolt
Shock Wave if first otherwise Thunderbolt , Quick Attack, Shock Wave , Quick Attack , Shock Wave
Beauty: (can be done with almost áll Weather Moves)
Geodude
- Sunny Day
- Flamethrower
- Selfdestruct
Sunny Day , Flamethrower , Sunny Day , Flamethrower , Selfdestruct
Solrock
- Sunny Day
- Flamethrower
- Overheat
- Explosion
Same as above, but Overheat when you won't get startled/stand last
Cute:
Whiscash (Anorith with Water Gun instead of Water Sport works same way)
- Water Sport
- Mud Sport
- Rest
- Snore
This one works REALLY well, first you start off with Snore. Then you start using the Rest/Snore or Water/Mud Sport combo, if you're about to get startled you use Rest/Snore, when not, go for Water/Mud Sport
Tough:
Muk (funny set with use of Condition-growing moves)
- Acid Armor
- Secret Power
- Rock Smash
This one wass just for fun but I won
, Acid Armor , Rock Smash , Acid Armor , Rock Smash , Secret Power (Rock Smash and Secret Power can be changed and you could go with Explosion with the set)
Aggron
- Harden
- Take Down
I won with this one the Master Contest (and being painted) while I got only 2 Conditionpoints... pretty easy, Take Down , Harden , Take Down , Harden , Take Down and just hope you won't get startled... could work with another move...
Shuppet
- Curse
- Spite
- Rain Dance
The Curse/Spite combo, works well because you won't get startled much... When you begin last it can be even better! If you don't start first take this:
Curse , Spite , Curse , Spite , Curse... use Rain Dance when appeal is at highest place...
I don't really have a Smart-Contest pokémon... I used a Barboach with Rest/Snore combo, but it's not bounded to type.
Although, I thought up, probably the best set for Smart:
Gengar/Haunter
- Shadow Punch
- Curse
- Spite
- Destiny Bond
However Curse and Spite are Tough, it's almost the best set here. Try to max out your Gengar so it will go first, then:
Shadow Punch , Curse , Spite , Curse , Destiny Bond
EDIT: Can someone explain something about pokéblocks... Let's say I got a Pokeblock with 12 Use and 24 Added Points with using a berry which main flavor is Spicy, and added flavor is Sour... how will the points distribute?