Lv. 100 blaziken, pelipper, breloom, swellow, salamence, manectric, ampharos, espeon, ursaring, walrein, roselia, venomoth, houndoom, dustox, ho-oh, entei, suicune, rapidash, umbreon, jirachi, starmie, gardevoir, pidgeot, cacturne, kingdra, lapras, jumpluff, dragonite, raichu, venusaur, ninetales
(well...truthfully only a couple of them are at Lv. 100, but the rest are either late 80's or in the 90's)
This is just in my emerald/FR/XD/colluseum games...There are also others I have in my old gold version which I no longer play. These include togetic, typhlosion, lanturn, butterfree, umbreon, octillary, articuno, lugia and some others.