345ash-greninja
Auto-Memories Doll
It's not just a matter of how much spotlight and screentime Rowlet gets and how many battles it'll participate in, but also how many episodes will focus on character developing the grass owl. Since Rowlet is a starter Pokemon, it's very likely that's going to get a fair amount of episodes dedicated to the owl, but there hasn't been any since its capture. The same goes for Litten and Rockruff. To be honest, Litten has more development than both Rowlet and Rockruff. I'm not saying that Litten is going to evolve before Rowlet and Rockruff, but right now, Litten shows more potential to evolve at the moment.
I don't think Litten has more chances of evolving than Rowlet at this point. It has just been caught, and though it has had quite some development, I highly doubt it will evolve without getting any good battles. I understand your point that Rowlet hasn't had many episodes focusing on it, but on the flip side, it has been a screenhogger to an extent in many episodes, being part of some funny gags, because of its comical quirky personality. It has also got a fair amount of battles- 1 Totem battle+1 Kahuna battle as a Rowlet. So I think, it probably has the best chance of evolving among Ash's team at this point.
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