Pros:
Croagunk. Jesus Christ Superstar: Sinnoh Edition Winner for 5 years running.
They FINALLY gave Wallace an appearance.
May and Jasmine, hooray!
They got a Steve Burton soundalike for Volkner, but that disappears when he gets happy again. :/
Reggie's sooooo handsome!
Looker is as charming as ever, and he beats up Galactic Grunts too.
Cons:
Ash doesn't look very cute, he looks and sounds like a guy who's on the cusp of puberty. Isn't he meant to be cute? At least Best Wishes got that right and made him look utterly huggable.
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Dawn's a whiny helpless disappointing (not hating on her, just disappointed. Don't be hatin') step down from the Freudian heroine I'd like to call May. As with Ash, this was fixed in Best Wishes with the deeply flawed yet likable jungle girl Iris, who reminds me of a mix of Hare and Guu from that one anime whose dub I can never seem to find.
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Brock was put into an uncomfortable Catch 22 situation: He's just THERE most of the time to take care of Ash and Dawn, and doesn't provide any importance at all to the saga which is made even more jarring with Croagunk's downright EPIC spars with Saturn's Toxicroak. I can understand the shock and outrage that it'd most likely cause if Brock left forever after AG, but demoting him to this is just even more outrageous. Again, Best Wishes (AKA what the writers wished upon when they wanted the best series ever for the fans) fixed this with Cilan, and it says a lot when the guy's more popular on the poll than Brock by a good margin.
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Paul was unnecessarily cruel (they could make a nicer character that still pushes Ash to the limit with his strategies) and his entire backstory is logically flawed. He seems to be more obsessed with power than the Ushiromiyas, and seeing him brutally disregard his brother's (who's a cherub in comparison) ambition and settling down to support Paul is just egh. I don't know whether or not Trip fixes this, but he is nicer (and more attractive looking and cute and I like him basically) and he doesn't dwell on his losses, unlike Paul who pours all the scalding blame onto his poor sla- Pokemon.
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Too many Pokemon from previous regions. I'd like to see the new Pokemon and what they're doing, not all these Hoenn and Johto and Kanto Pokemon doing filler stuff! Best Wishes fixes this by deliberately excluding every pre-Gen V Pokemon (except Pikachu/Meowth/a cameo of Giovanni's Persian) and making the new Pokemon hilarious Eagleland arseholes with personalities and traits previously only fully given to humans and Croagunk.
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Many other people have said this, and it needs no introduction: Lack of chemistry. The main reason why people loved the original trio was that it was three people with clearly defined goals that obviously had problems with eachother, creating a sitcom dynamic that was cherished by the kids growing up during the OG while the adults could enjoy the TRio's puns, gags and double entendres. The DP trio features absolutely none of this, and it's just three people journeying together for the convinience of it. This is by FAR my worst problem with Diamond and Pearl, and it basically reduces the anime to a merchandise driven kiddy show while the TRio (those brave souls) attempt to salvage what's left, but even then that still fails as they're demoted to appearing for the sake of appearing. Best Wishes again fixes this by, well, rebooting focking everything and turning Ash/Iris/Cilan into a trio the newer generations of Pokemon fans can look up to and enjoy, whilst making the TRio even more interesting than the past ten or so years could ever try.
This is just a musing about Paul and Silver. Perhaps they're saving this for a later region (or maybe not if Diamondshipping's semi-canon) but the comparisons with Silver are definitely there, and isn't it odd when Silver (the darkest rival in the series by far) is much nicer to his Pokemon than Paul is? I think the guy might have a chance if the anime is going to end sooner or later and they want Ash's final rival to be someone more memorable than Gary, who has unfortunately fixed all bridges with Ash and is now at a convent studying diligently for the Professorhood.
...God, this post feels really long!