Okay, so I decided to give photoshop a shot, this is just me playing around with the brush and the retouch button mind you. Give me some time to learn a little more and I'll get a bit more detailed and all that =P
Very cute! : D
The eye sort of creeps me out, but whatever. The shading is good; nice effect with the brush.
I agree the eye is creepy but so cute~! nice job keep it up!
I think it's not the eyes that are really what's creepy, it's more the size of the head. But then in turn that would make you want to make the eyes bigger in proportion to the head. In general, Mew's head is slightly out of proportion to it's petite body, but this is just a tad too far. :< Other than that I really love the almost furry texture you gave it, it's just perfect. Not too much, but just enough. I hope you'll get the hang of photoshop but I doubt that will take long seeing this as just a beginning fiddling picture.