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When exactly did Pikachu learn Thunderbolt?

I've been watching for a while, But I never really knew the first episode where Pikachu stopped using thundershock and began using thunderbolt, Does anyone know when that was?


I'll learn you good!
Back in the early Kanto days, Pikachu pretty much used both attacks interchangably.
When it got Super Charged by the water wheel in the Pewter Gym ep.