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Yes, catching Pokemon, like many things in the Pokemon games, is based totally on luck. You can have a Pokemon caught at full health by using only one ball, or you can catch a Pokemon at very low health by using fifty Pokeballs.
So just keep tossing Safari Balls at Chanseys when you find one, and if it breaks out, try again. Keep doing that until you catch one.
You can throw rocks at them if you want, it increases your chances of catching one, but it also increases the chance that it'll flee from battle. I'd just stick with tossing as many Safari Balls as you can.
NEVER NEVER NEVER EVER USE BAIT OR ROCKS!!! Believe me, I had this same problem and someone told me to not throw rocks or bait, only Safari Balls. I now have three Chansey. One of them even had a lucky egg! It's all luck but don't chance it.