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For silverpowder, the bug catcher on route 120 (forget his name) (the one with the 3 Surskits) will have one on his Masquarein on the 5th fight and forward.
Blackbelt Nob's Machamp will hold a Blackbelt from the 5th fight onward.
The Dragon Tamer in meteor falls's Shelgon will hold dragon fang from the 5th fight onward.
As mentioned, the rich boy and lady's Linoone hold one. However this is for every battle, not just 5th and after.
A few random trainers have Sitrus berries on their Pokemon.
Also, if you're playing emerald, try using thief on some of Flannary's Pokemon. Torkoal, Camerupt and Magcargo I think are the ones.
Look what I do if I want some more money:
1.go to the rich boy
2. use thief on his linoone
3.battle with a pokemon that is holding an amulet coin
After that you are so rich...